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Real life interaction is nor black nor white. As such there is no one size fits all approach. There are however general behaviourial rules that apply in order to seduce girls.
My best advice is to read the lounge section for there are at regular basis good in depth posts on seduction and human psychology. Read some commercial material aswell (I've for example also read The game, Rules to the game, Double Your Dating and 60's full manifesto) try to grasp the concepts behind the lines. Make connections between all of these methods.
Analyse what happens around you based on your pick-up books. Work on your social intelligence and thus learn how to behave in different situations.
Excellent advice here. + 1 Well said P-style.
I'd also like to add for the OP. To let your instincts come into play. We are all fined tuned unconsciously to interact with the opposite sex, the less you can let your conscious thoughts interfere and just see it as interacting with another human being rather then seeing it as a potential seduction, the better you will be suited to the interaction. When a man initiates a conversation with a woman, physical interest is pretty much already implied, in these particular situations, it is wise to be indirect. Try to create instant comfort, your body and unconscious gestures will do the rest. Look for signs of interest, if they are sufficient, then become direct with your intentions.
If your time is limited and you have to make it a cold approach, make it a positive experience, you don't always have to go in for the close. Make it positive for the both of you, you never know when you may see this woman again. If you got into her head in a good way, chances are if she see's you again, she will remember you.
Just remember, you are in this for the long haul, it's not always about getting the girl, as much as it is about learning to become a desirable man. Learn from every experience you have, try to take something positive out of every single one.
Good luck.