If you aren't feeling confident that you can make things move faster through facebook i would try to avoid it. If you think you may have misread a signal then finding her number off someone else or finding her on facebook might seem a little creepy. If you think there will be another situation in which you can see her naturally then i would wait for that, unless it's a long way away.
However, if you are confident that you can step it up on facebook then go ahead. Also, while on facebook you could pretend you are on your phone's facebook and the messenger is malfunctioning. Then you could say something like "is there any other way we can talk?". Either she will arrange a meeting or give you her number, either is good. I tend to find girls get closer to people they text or call rather than facebooking so even if the conversation doesnt change much youll stand out among the other facebooking AFCs.
