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You're getting ahead of yourself. Most dudes, PUAs included can hardly handle one woman, let alone 2.
Having 2 girls (or guys, in your case), who you presumably barely know will just send off friend vibe to either one. It'd be another thing entirely if you were going to a large venue such as a club and inviting a bunch of people, but to invite 2 girls to a more intimate gathering such as a super bowl game has FAIL written all over it. Go with the 2nd girl, the one who's a definite 'yes'. The other girl tell her you've made other plans but should get together some other time (specify the time if possible).
Having a relationship with 2 women at the same time ( being emotionally involved ) is difficult.
Having 5 fuck-buddies and handling them is easy.
If you want just sex ... go with the one that is hotter.
If you want an emotional connection ( relationship ) then go with the one you have more in common and appeals to you not just by the way she looks.