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I would lean back when you first meet her to establish that you are the Alpha-leader like LA Tripp said, then mirror when you start building comfort. Thats what I do.
Exactly. If you start to mirror too soon, then it can actually be off-putting, because you get this weird feeling like this person is following you, or making fun of you. You start to do it at the right time and do it well, you can carry on a casual conversation, while making them feel this incredible physical attraction, even if they don't consider you someone they normally would be attracted to, just because you are in sync and it feels like your chemistry is much better than it normally would have been.